| Literature DB >> 27367442 |
Qing Pan1, Leon Freitag, Tanja Kowacs, Jane C Falgenhauer, Jeroen P Korterik, Derck Schlettwein, Wesley R Browne, Mary T Pryce, Sven Rau, Leticia González, Johannes G Vos, Annemarie Huijser.
Abstract
The contrasting early-time photodynamics of two related Ru/Pt photocatalysts with very different photocatalytic H2 generation capabilities are reported. Ultrafast equilibration (535 ± 17 fs) creates an electron reservoir on the peripheral ligands of the ester substituted complex, allowing a dramatic increase in photocatalytic performance. This insight opens the way towards a novel design strategy for H2 generating molecular photocatalysts.Entities:
Year: 2016 PMID： 27367442 DOI： 10.1039/c6cc05222c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222