Literature DB >> 27364983

[2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment.

Paul Kahl1, J Philipp Wagner1, Ciro Balestrieri2, Jonathan Becker3, Heike Hausmann1, Graham J Bodwell4, Peter R Schreiner5.   

Abstract

The fusion of the sp(3) -hybridized parent diamondoid adamantane with the sp(2) -hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  allotropy; graphene; materials science; strained molecules; structure elucidation

Year:  2016        PMID: 27364983     DOI: 10.1002/anie.201602201

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  1 in total

Review 1.  Direct radical functionalization methods to access substituted adamantanes and diamondoids.

Authors:  William K Weigel; Hoang T Dang; Abigail Feceu; David B C Martin
Journal:  Org Biomol Chem       Date:  2021-12-22       Impact factor: 3.890

  1 in total

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