Literature DB >> 27364730

Visible-Light-Promoted Direct Amination of Phenols via Oxidative Cross-Dehydrogenative Coupling Reaction.

Yating Zhao1, Binbin Huang1, Chao Yang1, Wujiong Xia1.   

Abstract

A transition-metal-free approach was disclosed for intermolecular aryl C-N bonds formation between phenols and cyclic anilines via cross-dehydrogenative coupling (CDC) amination that was mediated by visible light, wherein K2S2O8 served as an external oxidant. The salient features of this protocol include circumventing the requirement for prefunctionalized starting materials and achieving single regioselectivity of amination adducts at room temperature.

Entities:  

Year:  2016        PMID： 27364730     DOI： 10.1021/acs.orglett.6b01371

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  15 in total

1.  Photocatalytic Oxidative Dearomatization of Orcinaldehyde Derivatives.

Authors:  Summer A Baker Dockrey; Alison R H Narayan
Journal:  Org Lett       Date:  2020-04-15       Impact factor: 6.005

2.  Intermolecular Aryl C-H Amination through Sequential Iron and Copper Catalysis.

Authors:  Mohamed A B Mostafa; Ewen D D Calder; Daugirdas T Racys; Andrew Sutherland
Journal:  Chemistry       Date:  2016-12-16       Impact factor: 5.236

3.  Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents.

Authors:  Rongwei Jin; Christina L Bub; Frederic W Patureau
Journal:  Org Lett       Date:  2018-04-27       Impact factor: 6.005

4.  Electrooxidative para-selective C-H/N-H cross-coupling with hydrogen evolution to synthesize triarylamine derivatives.

Authors:  Kun Liu; Shan Tang; Ting Wu; Shengchun Wang; Minzhu Zou; Hengjiang Cong; Aiwen Lei
Journal:  Nat Commun       Date:  2019-02-07       Impact factor: 14.919

5.  HBF4- and AgBF4-Catalyzed ortho-Alkylation of Diarylamines and Phenols.

Authors:  Christian K Rank; Bünyamin Özkaya; Frederic W Patureau
Journal:  Org Lett       Date:  2019-08-20       Impact factor: 6.005

6.  The cumene/O2 system: a very simple tool for the radical chain oxidation of some functional groups.

Authors:  A Malekafzali; K Malinovska; F W Patureau
Journal:  New J Chem       Date:  2017-06-30       Impact factor: 3.591

7.  Mechanism of the Dehydrogenative Phenothiazination of Phenols.

Authors:  Monalisa Goswami; Alexander Konkel; Maryam Rahimi; Marie-Laure Louillat-Habermeyer; Harald Kelm; Rongwei Jin; Bas de Bruin; Frederic W Patureau
Journal:  Chemistry       Date:  2018-07-25       Impact factor: 5.236

8.  Visible Light Induced Metal-Free Carbene N-Carbazolation.

Authors:  Claire Empel; Frederic W Patureau; Rene M Koenigs
Journal:  J Org Chem       Date:  2019-08-15       Impact factor: 4.354

9.  Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives.

Authors:  Kotaro Kikushima; Haruka Koyama; Kazuki Kodama; Toshifumi Dohi
Journal:  Molecules       Date:  2021-03-04       Impact factor: 4.411

10.  Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings.

Authors:  Christina L Bub; Vinzenz Thönnißen; Frederic W Patureau
Journal:  Org Lett       Date:  2020-11-16       Impact factor: 6.005
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