Literature DB >> 27358063

Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.

F Pointillart1, X Liu, M Kepenekian, B Le Guennic, S Golhen, V Dorcet, T Roisnel, O Cador, Z You, J Hauser, S Decurtins, L Ouahab, S-X Liu.   

Abstract

A mononuclear Fe(ii) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

Entities:  

Year:  2016        PMID： 27358063     DOI： 10.1039/c6dt00920d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Field-Induced Dysprosium Single-Molecule Magnet Based on a Redox-Active Fused 1,10-Phenanthroline-Tetrathiafulvalene-1,10-Phenanthroline Bridging Triad.

Authors:  Bertrand Lefeuvre; Olivier Galangau; Jessica Flores Gonzalez; Vincent Montigaud; Vincent Dorcet; Lahcène Ouahab; Boris Le Guennic; Olivier Cador; Fabrice Pointillart
Journal:  Front Chem       Date:  2018-11-13       Impact factor: 5.221

2.  Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron(ii) incorporating tetrathiafulvalene.

Authors:  Ya-Ru Qiu; Long Cui; Pei-Yu Cai; Fei Yu; Mohamedally Kurmoo; Chanel F Leong; Deanna M D'Alessandro; Jing-Lin Zuo
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825
  2 in total

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