Literature DB >> 27321954

Fast-Geomimicking using Chemistry in Supercritical Water.

Angela Dumas1, Marie Claverie2, Cédric Slostowski1, Guillaume Aubert1, Cristel Careme2, Christophe Le Roux3, Pierre Micoud3, François Martin4, Cyril Aymonier5.   

Abstract

Herein we introduce a powerful and fast method to produce nanominerals using a bottom up approach. The supercritical hydrothermal flow synthesis is exploited to produce model nanominerals by mimicking natural environments at high temperatures under pressure. This innovative concept is demonstrated with the talc synthesis; this represents a major technical breakthrough since it allows decreasing the mineral-synthesis time from tens of hours to tens of seconds. Through this example, we show these nanominerals exhibit new crystal-chemistry signals and new properties. This approach provides a means to reproduce the early stages of formation of minerals in different natural environments from sedimentary environments (low temperature and pressure) to hydrothermal/metamorphic environments (high temperature and high pressure).
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  clay; hydrophilic nanominerals; hydrothermal synthesis; supercritical water; talc

Year:  2016        PMID: 27321954     DOI: 10.1002/anie.201604096

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336



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