| Literature DB >> 27314283 |
Xiao Zhang1, Mengmeng Zhen1, Jinwu Bai1, Shaowei Jin2, Lu Liu1.
Abstract
Hollow and hybrid nanomaterials are excellent electrocatalysts on account of their novel electrocatalytic properties compared with homogeneous solid nanostructures. In this report, NiSe-Ni3Se2 hybrid nanostructure with morphology of hollow hexagonal nanodisk was synthesized in situ on graphene. A series of NiSe-Ni3Se2/RGO with different phase constitutions and nanostructures were obtained by controlling the durations of solvothermal treatment. Because of their unique hollow and hybrid structure, NiSe-Ni3Se2/RGO hollow nanodisks exhibited higher electrocatalytic performance than NiSe/RGO and solid NiSe-Ni3Se2/RGO nanostructure for reducing I3(-) as counter cell (CE) of dye-sensitized solar cells (DSSCs). Additionally, NiSe-Ni3Se2/RGO hollow nanodisks achieved much lower charge transfer resistance (Rct = 0.68 Ω) and higher power conversion efficiency (PCE) (7.87%) than those of Pt (Rct = 1.41 Ω, PCE = 7.28%).Entities:
Keywords: NiSe-Ni3Se2; electrocatalyst; graphene; hollow hybrid nanostructure; mesoporous hexagon
Year: 2016 PMID: 27314283 DOI: 10.1021/acsami.6b02350
Source DB: PubMed Journal: ACS Appl Mater Interfaces ISSN: 1944-8244 Impact factor: 9.229