| Literature DB >> 27310000 |
Maren Rasmussen1, Christian Näther1, Jan van Leusen2, Ulrike Warzok3, Christoph A Schalley3, Paul Kögerler2, Wolfgang Bensch1.
Abstract
Minimal-nuclearity vanadato-tungstate clusters in [{V(IV)(dien)}4WO14]·4H2O () and [{V(IV)(dien)}4WO20]·6H2O () feature cores of edge-sharing WO6 octahedra, surrounded by a ring of four vanadyl groups. Surprisingly, the V(iv) centers in both and are ferromagnetically coupled, in contrast to all other known vanadato-polyoxotungstates featuring the ubiquituos V-O-W-O-V exchange pathways.Entities:
Year: 2016 PMID： 27310000 DOI： 10.1039/c6dt02282k
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390