Literature DB >> 27284590

Adsorption of two gas molecules at a single metal site in a metal-organic framework.

Tomče Runčevski1, Matthew T Kapelewski, Rodolfo M Torres-Gavosto, Jacob D Tarver, Craig M Brown, Jeffrey R Long.   

Abstract

One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules-specifically hydrogen, methane, or carbon dioxide.

Entities:  

Year:  2016        PMID： 27284590     DOI： 10.1039/c6cc02494g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Defects Formation and Amorphization of Zn-MOF-74 Crystals by Post-Synthetic Interactions with Bidentate Adsorbates.

Authors:  Jonathan B Lefton; Kyle B Pekar; Uroob Haris; Mary E Zick; Phillip J Milner; Alexander R Lippert; Ljupčo Pejov; Tomče Runčevski
Journal:  J Mater Chem A Mater       Date:  2021-02-03

2.  Rational Design of a Low-Cost, High-Performance Metal-Organic Framework for Hydrogen Storage and Carbon Capture.

Authors:  Matthew Witman; Sanliang Ling; Andrzej Gladysiak; Kyriakos C Stylianou; Berend Smit; Ben Slater; Maciej Haranczyk
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2016-12-16       Impact factor: 4.126

3.  IRMOF-74(n)-Mg: a novel catalyst series for hydrogen activation and hydrogenolysis of C-O bonds.

Authors:  Vitalie Stavila; Michael E Foster; Jonathan W Brown; Ryan W Davis; Jane Edgington; Annabelle I Benin; Ryan A Zarkesh; Ramakrishnan Parthasarathi; David W Hoyt; Eric D Walter; Amity Andersen; Nancy M Washton; Andrew S Lipton; Mark D Allendorf
Journal:  Chem Sci       Date:  2019-09-03       Impact factor: 9.825

4.  Structural resolution and mechanistic insight into hydrogen adsorption in flexible ZIF-7.

Authors:  Ryan A Klein; Sarah Shulda; Philip A Parilla; Pierre Le Magueres; Rachelle K Richardson; William Morris; Craig M Brown; C Michael McGuirk
Journal:  Chem Sci       Date:  2021-11-24       Impact factor: 9.825

5.  Self-adjusting binding pockets enhance H2 and CH4 adsorption in a uranium-based metal-organic framework.

Authors:  Dominik P Halter; Ryan A Klein; Michael A Boreen; Benjamin A Trump; Craig M Brown; Jeffrey R Long
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825
  5 in total

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