Graphene-based porous materials with tunable surface area and CO2 adsorption properties synthesized by fluorine displacement reaction with various diamines.

A mild, operationally simple and controllable protocol for preparing graphene-based porous materials is essential to achieve a good pore-design development. In this paper, graphene-based porous materials with tunable surface area were constructed by the intercalation of fluorinated graphene (FG) based on the reaction of reactive CF bonds attached to graphene sheets with various amine-terminated molecules. In the porous materials, graphene sheets are like building blocks, and the diamines covalently grafted onto graphene framework act as pillars. Various diamines are successfully grafted onto graphene sheets, but the grafting ratio of diamines and reduction degree of FG differ greatly and depend on the chemical reactivity of diamines. Pillared diamine molecules chemically anchor at one end and are capable of undergoing a different reaction on the other end, resulting in three different conformations of graphene derivatives. Nitrogen sorption isotherms revealed that the surface area and pore distribution of the obtained porous materials depend heavily on the size and structure of diamine pillars. CO2 uptake capacity characterization showed that ethylenediamine intercalated FG achieved a high CO2 uptake density of 18.0 CO2 molecules per nm(2) at 0°C and 1.1bars, and high adsorption heat, up to 46.1kJmol(-1) at zero coverage.