Literature DB >> 27279018

Manganese-catalyzed regiospecific sp(3) C-S bond formation through C-C bond cleavage of cyclobutanols.

Rongguo Ren1, Zhen Wu1, Chen Zhu2.   

Abstract

A manganese-catalyzed regioselective sp(3) C-S bond formation through C-C bond cleavage of cyclobutanols is described. A variety of primary and secondary alkyl thioethers are efficiently prepared under mild reaction conditions. The mechanistic pathways involving radical-mediated tandem C-C bond cleavage and C-S bond formation are proposed.

Entities:  

Year:  2016        PMID： 27279018     DOI： 10.1039/c6cc01843b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Catalytic generation of alkoxy radicals from unfunctionalized alcohols.

Authors:  Elaine Tsui; Huaiju Wang; Robert R Knowles
Journal:  Chem Sci       Date:  2020-09-21       Impact factor: 9.825

2.  Redox-neutral manganese-catalyzed synthesis of 1-pyrrolines.

Authors:  Tingting Feng; Canxiang Liu; Zhen Wu; Xinxin Wu; Chen Zhu
Journal:  Chem Sci       Date:  2022-02-09       Impact factor: 9.825

3.  Visible light-promoted ring-opening functionalization of unstrained cycloalkanols via inert C-C bond scission.

Authors:  Dongping Wang; Jincheng Mao; Chen Zhu
Journal:  Chem Sci       Date:  2018-06-11       Impact factor: 9.825
  3 in total

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