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Literature DB >> 27269443

Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2.

Marino Börjesson¹, Toni Moragas¹, Ruben Martin^1,2.

Abstract

A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO2 at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.

Entities: Chemical

Year: 2016 PMID： 27269443 DOI： 10.1021/jacs.6b04088

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

26 in total

1. Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling.

Authors: Kirk W Shimkin; John Montgomery
Journal: J Am Chem Soc Date: 2018-05-31 Impact factor: 15.419

2. Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp² )-C(sp³ )Coupling Reactions.

Authors: Megan Mohadjer Beromi; Gary W Brudvig; Nilay Hazari; Hannah M C Lant; Brandon Q Mercado
Journal: Angew Chem Int Ed Engl Date: 2019-03-27 Impact factor: 15.336

3. Cross-Electrophile Coupling of Unactivated Alkyl Chlorides.

Authors: Holt A Sakai; Wei Liu; Chi Chip Le; David W C MacMillan
Journal: J Am Chem Soc Date: 2020-06-26 Impact factor: 15.419

4. Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies.

Authors: David J Charboneau; Gary W Brudvig; Nilay Hazari; Hannah M C Lant; Andrew K Saydjari
Journal: ACS Catal Date: 2019-03-14 Impact factor: 13.084

5. Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies.

Authors: Qiao Lin; Yue Fu; Peng Liu; Tianning Diao
Journal: J Am Chem Soc Date: 2021-08-25 Impact factor: 15.419

Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2.

1. Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling.

2. Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp² )-C(sp³ )Coupling Reactions.

3. Cross-Electrophile Coupling of Unactivated Alkyl Chlorides.

4. Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies.

5. Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies.

6. Direct Carbon Isotope Exchange through Decarboxylative Carboxylation.

7. Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity.

8. Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors.

9. Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides.

Review 10. Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO₂.

Review 10. Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2.

Review 10. Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO₂.