Influence of Surface Treatment on Magnetic Properties of Fe3O4 Nanoparticles Synthesized by Electrochemical Method.

The changes of magnetic properties in magnetite nanoparticles during two different stabilization processes were investigated. Magnetic nanoparticles (MNPs) were obtained by electrochemical synthesis from two kinds of salts: (CH3)4NCl and NaCl. After that, two methods-steric and electrostatic-were used to stabilize MNPs with oleic acid (OA) and sodium hydroxide (NaOH), respectively. As a consequence, aqueous and organic dispersions were obtained after surface modification. The coated nanoparticles were characterized by TEM, zeta potential, thermogravimetry analysis (TGA), cyclic voltammetry (CV), magnetization measurements, and infrared and Mössbauer spectroscopy. The results showed that the particles were between 8 and 13 nm in size. In addition, the MNPs were coated with negative charge layers from NaOH by physisorption and coated with carboxylate groups from OA by the chemisorption process, and hence, they exhibited different reactivity and behavior depending on the nature of the electrolyte used in the electrochemical synthesis. Furthermore, the uncoated and coated MNPs had a narrow size distribution. Additionally, the saturation magnetization values showed dependence on the magnetite synthesis conditions and surface modifiers.