| Literature DB >> 27266834 |
Liangliang Shi, Baiquan Wang1.
Abstract
An efficient Rh(III)-catalyzed synthetic method for indoloquinoline derivatives from readily available indoles and isoxazoles was developed. This annulation procedure undergoes tandem C-H activation, cyclization, and condensation steps. In this domino cyclization reaction, water is an efficient solvent. A catalytically competent five-membered rhodacycle has been isolated and characterized, thus revealing a key intermediate in the catalytic cycle.Entities:
Year: 2016 PMID: 27266834 DOI: 10.1021/acs.orglett.6b01234
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005