Literature DB >> 27251100

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters.

Xing-Ping Zeng1, Zhong-Yan Cao1, Yu-Hui Wang1, Feng Zhou1, Jian Zhou1,2.   

Abstract

This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and meso-compounds, highlights the power and potential of this strategy in the total synthesis of natural products and biologically active compounds, and outlines the synthetic opportunities still available.

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Year:  2016        PMID： 27251100     DOI： 10.1021/acs.chemrev.6b00094

Source DB:  PubMed          Journal:  Chem Rev        ISSN： 0009-2665            Impact factor:   60.622


  59 in total

1.  Development of the Regiodivergent Asymmetric Prenylation of 3-Substituted Oxindoles.

Authors:  Barry M Trost; Walter H Chan; Sushant Malhotra
Journal:  Chemistry       Date:  2017-03-06       Impact factor: 5.236

2.  Controllable, Sequential, and Stereoselective C-H Allylic Alkylation of Alkenes.

Authors:  Ling Qin; Mohammed Sharique; Uttam K Tambar
Journal:  J Am Chem Soc       Date:  2019-10-15       Impact factor: 15.419

3.  Biomimetic Desymmetrization of a Carboxylic Acid.

Authors:  Matthew T Knowe; Michael W Danneman; Sarah Sun; Maren Pink; Jeffrey N Johnston
Journal:  J Am Chem Soc       Date:  2018-02-05       Impact factor: 15.419

4.  Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.

Authors:  Jiajie Feng; Michael Holmes; Michael J Krische
Journal:  Chem Rev       Date:  2017-09-14       Impact factor: 60.622

5.  Cu-Catalyzed Diastereo- and Enantioselective Reactions of γ,γ-Disubstituted Allyldiboron Compounds with Ketones.

Authors:  Joseph M Zanghi; Simon J Meek
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-24       Impact factor: 15.336

6.  Catalytic Asymmetric Staudinger-aza-Wittig Reaction for the Synthesis of Heterocyclic Amines.

Authors:  Lingchao Cai; Kui Zhang; Shuming Chen; Romain J Lepage; K N Houk; Elizabeth H Krenske; Ohyun Kwon
Journal:  J Am Chem Soc       Date:  2019-06-07       Impact factor: 15.419

7.  Enantio- and Diastereoselective Synthesis of Functionalized Carbocycles by Cu-Catalyzed Borylative Cyclization of Alkynes with Ketones.

Authors:  Joseph M Zanghi; Shuang Liu; Simon J Meek
Journal:  Org Lett       Date:  2019-06-14       Impact factor: 6.005

8.  Local Desymmetrization through Diastereotopic Group Selection: An Enabling Strategy for Natural Product Synthesis.

Authors:  Matthew A Horwitz; Jeffrey S Johnson
Journal:  European J Org Chem       Date:  2017-02-07

9.  Diastereo- and Enantioselective Synthesis of Homoallylic Amines Bearing Quaternary Carbon Centers.

Authors:  Jacob C Green; Joseph M Zanghi; Simon J Meek
Journal:  J Am Chem Soc       Date:  2020-01-17       Impact factor: 15.419

10.  Diastereo-, Enantio-, and anti-Selective Formation of Secondary Alcohol and Quaternary Carbon Stereocenters by Cu-Catalyzed Additions of B-Substituted Allyl Nucleophiles to Carbonyls.

Authors:  Emilie Wheatley; Joseph M Zanghi; Simon J Meek
Journal:  Org Lett       Date:  2020-11-18       Impact factor: 6.005
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