Literature DB >> 27228548

Photochemical Cleavage of Benzylic C-N Bond To Release Amines.

Pengfei Wang1, Dattatray A Devalankar1, Wenya Lu1.   

Abstract

The 3-(diethylamino)benzyl (DEABn) group has been studied for releasing primary, secondary, and tertiary amines by direct photochemical breaking of the benzylic C-N bond. While photochemical release of primary and secondary amines provides high yields in methanol, release of tertiary amines in MeCN/water can improve yields and reduce the undesired dealkylation side reaction.

Entities:  

Year:  2016        PMID： 27228548     DOI： 10.1021/acs.joc.6b00508

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Visible-to-NIR-Light Activated Release: From Small Molecules to Nanomaterials.

Authors:  Roy Weinstain; Tomáš Slanina; Dnyaneshwar Kand; Petr Klán
Journal:  Chem Rev       Date:  2020-10-30       Impact factor: 60.622

2.  Mass spectrometric analysis of acid-assisted photochemical release of the trimethyl lock system on the monolayers on gold.

Authors:  Geunhyeok Yu; Woon-Seok Yeo
Journal:  RSC Adv       Date:  2020-05-11       Impact factor: 3.361
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.