Literature DB >> 27206061

Recyclable Crosslinked Polymer Networks via One-Step Controlled Radical Polymerization.

Kailong Jin1, Lingqiao Li1, John M Torkelson2.   

Abstract

A nitroxide-mediated polymerization strategy allows one-step synthesis of recyclable crosslinked polymeric materials from any monomers or polymers that contain carbon-carbon double bonds amenable to radical polymerization. The resulting materials with dynamic covalent bonds can show full property recovery after multiple melt-reprocessing recycles. This one-step strategy provides for both robust, relatively sustainable recyclability of crosslinked polymers and design of networks for advanced technologies.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  compression molding; dynamic covalent bonds; nitroxide-mediated polymerization; recyclable crosslinked polymers; uniform polymer networks

Year:  2016        PMID: 27206061     DOI: 10.1002/adma.201600871

Source DB:  PubMed          Journal:  Adv Mater        ISSN: 0935-9648            Impact factor:   30.849


  6 in total

1.  Light-Stimulated Permanent Shape Reconfiguration in Cross-Linked Polymer Microparticles.

Authors:  Lewis Michael Cox; Xiaohao Sun; Chen Wang; Nancy Sowan; Jason P Killgore; Rong Long; Heng-An Wu; Christopher N Bowman; Yifu Ding
Journal:  ACS Appl Mater Interfaces       Date:  2017-04-12       Impact factor: 9.229

2.  Effects of systematically varied thiourethane-functionalized filler concentration on polymerization behavior and relevant clinical properties of dental composites.

Authors:  S H Lewis; Fugolin App; S Lam; C Scanlon; J L Ferracane; C S Pfeifer
Journal:  Mater Des       Date:  2020-10-21       Impact factor: 7.991

3.  Recyclable carbon fibre composites enabled by cystine containing epoxy matrices.

Authors:  Martin L Henriksen; Jakob E Friis; Astrid Voss; Mogens Hinge
Journal:  RSC Adv       Date:  2019-10-02       Impact factor: 3.361

4.  A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions.

Authors:  Jian-Cheng Lai; Lan Li; Da-Peng Wang; Min-Hao Zhang; Sheng-Ran Mo; Xue Wang; Ke-Yu Zeng; Cheng-Hui Li; Qing Jiang; Xiao-Zeng You; Jing-Lin Zuo
Journal:  Nat Commun       Date:  2018-07-13       Impact factor: 14.919

5.  Dynamic multiphase semi-crystalline polymers based on thermally reversible pyrazole-urea bonds.

Authors:  Wen-Xing Liu; Zhusheng Yang; Zhi Qiao; Long Zhang; Ning Zhao; Sanzhong Luo; Jian Xu
Journal:  Nat Commun       Date:  2019-10-18       Impact factor: 14.919

6.  Upcycling of dynamic thiourea thermoset polymers by intrinsic chemical strengthening.

Authors:  Haijun Feng; Ning Zheng; Wenjun Peng; Chujun Ni; Huijie Song; Qian Zhao; Tao Xie
Journal:  Nat Commun       Date:  2022-01-19       Impact factor: 14.919

  6 in total

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