Literature DB >> 27194643

Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers.

Keren Zhang1, Samantha J Talley, Ya Peng Yu, Robert B Moore, Mitsuhiro Murayama, Timothy E Long.   

Abstract

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates. Intermolecular hydrogen bonding formed thymine-adenine triplets and promoted self-assembly into well-defined lamellae consisting of poly(n-butyl acrylate) soft domains and complementary nucleobase hard domains, while thymine-adenine duplets contributed to superior mechanical properties.

Entities:  

Year:  2016        PMID: 27194643     DOI: 10.1039/c6cc03502g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Sequence-defined vinyl sulfonamide click nucleic acids (VS-CNAs) and their assembly into dynamically responsive materials.

Authors:  Bryan P Sutherland; Paige J LeValley; Derek J Bischoff; April M Kloxin; Christopher J Kloxin
Journal:  Chem Commun (Camb)       Date:  2020-09-24       Impact factor: 6.222

2.  Fabrication of Ordered Nanopattern by using ABC Triblock Copolymer with Salt in Toluene.

Authors:  Hailiang Huang; Benbin Zhong; Xihong Zu; Hongsheng Luo; Wenjing Lin; Minghai Zhang; Yazhou Zhong; Guobin Yi
Journal:  Nanoscale Res Lett       Date:  2017-08-15       Impact factor: 4.703

3.  Reversibly Manipulating the Surface Chemistry of Polymeric Nanostructures via a "Grafting To" Approach Mediated by Nucleobase Interactions.

Authors:  Zan Hua; Robert Keogh; Zhen Li; Thomas R Wilks; Guosong Chen; Rachel K O'Reilly
Journal:  Macromolecules       Date:  2017-04-18       Impact factor: 5.985

4.  Synthesis and surface characterization of new triplex polymer of Ag(I) and mixture nucleosides: cytidine and 8-bromoguanosine.

Authors:  Lamia L G Al-Mahamad
Journal:  Heliyon       Date:  2019-05-15
  4 in total

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