| Literature DB >> 27194643 |
Keren Zhang1, Samantha J Talley, Ya Peng Yu, Robert B Moore, Mitsuhiro Murayama, Timothy E Long.
Abstract
ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates. Intermolecular hydrogen bonding formed thymine-adenine triplets and promoted self-assembly into well-defined lamellae consisting of poly(n-butyl acrylate) soft domains and complementary nucleobase hard domains, while thymine-adenine duplets contributed to superior mechanical properties.Entities:
Year: 2016 PMID: 27194643 DOI: 10.1039/c6cc03502g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222