Literature DB >> 27191227

tert-Butyl Nitrite: Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker-Tsuji Oxidation.

Xiao-Shan Ning1, Mei-Mei Wang1, Chuan-Zhi Yao1, Xian-Min Chen1, Yan-Biao Kang1.   

Abstract

An aldehyde-selective aerobic Wacker-Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature.

Entities:  

Year:  2016        PMID: 27191227     DOI: 10.1021/acs.orglett.6b01165

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  Trace Ethylene Sensing via Wacker Oxidation.

Authors:  Darryl Fong; Shao-Xiong Luo; Rafaela S Andre; Timothy M Swager
Journal:  ACS Cent Sci       Date:  2020-03-18       Impact factor: 14.553

2.  Asymmetric Syntheses of (+)- and (-)-Collybolide Enable Reevaluation of kappa-Opioid Receptor Agonism.

Authors:  Sophia L Shevick; Stephan M Freeman; Guanghu Tong; Robin J Russo; Laura M Bohn; Ryan A Shenvi
Journal:  ACS Cent Sci       Date:  2022-07-18       Impact factor: 18.728

3.  The formyloxyl radical: electrophilicity, C-H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes.

Authors:  Miriam Somekh; Mark A Iron; Alexander M Khenkin; Ronny Neumann
Journal:  Chem Sci       Date:  2020-10-02       Impact factor: 9.825

4.  Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH.

Authors:  Zhi-Qiang Wang; Jiang-Xi Yu; Shan-Qin Bai; Bang Liu; Cheng-Yong Wang; Jin-Heng Li
Journal:  ACS Omega       Date:  2020-10-29
  4 in total

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