Literature DB >> 27169696

A Trifluoromethylcarbene Source.

Yaya Duan1, Jin-Hong Lin1, Ji-Chang Xiao1, Yu-Cheng Gu2.   

Abstract

The trifluoromethylcarbene (:CHCF3) was found to be conveniently generated from (2,2,2-trifluoroethyl)diphenyl-sulfonium triflate (Ph2S(+)CH2CF3 (-)OTf), which was successfully applied in Fe-catalyzed cyclopropanation of olefins, giving the corresponding trifluoromethylated cyclopropanes in high yields.

Entities:  

Year:  2016        PMID： 27169696     DOI： 10.1021/acs.orglett.6b01042

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

Review 2.  Sulfur-Based Ylides in Transition-Metal-Catalysed Processes.

Authors:  James D Neuhaus; Rik Oost; Jérémy Merad; Nuno Maulide
Journal:  Top Curr Chem (Cham)       Date:  2018-04-13

3.  A Catalytic Cross-Olefination of Diazo Compounds with Sulfoxonium Ylides.

Authors:  James D Neuhaus; Adriano Bauer; Alexandre Pinto; Nuno Maulide
Journal:  Angew Chem Int Ed Engl       Date:  2018-11-08       Impact factor: 15.336

Review 4.  Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group.

Authors:  Mário M Q Simões; Daniel T G Gonzaga; Mariana F C Cardoso; Luana da S M Forezi; Ana T P C Gomes; Fernando de C da Silva; Vítor F Ferreira; Maria G P M S Neves; José A S Cavaleiro
Journal:  Molecules       Date:  2018-03-29       Impact factor: 4.411
  4 in total

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