| Literature DB >> 27159115 |
Hui Guo1, Nicolas Sanson1, Dominique Hourdet1, Alba Marcellan1.
Abstract
A novel mode of gel toughening displaying crack bifurcation is highlighted in phase-separated hydrogels. By exploring original covalent network topologies, phase-separated gels under isochoric conditions demonstrate advanced thermoresponsive mechanical properties: excellent fatigue resistance, self-healing, and remarkable fracture energies. Beyond the phase-transition temperature, the fracture proceeds by a systematic crack-bifurcation process, unreported so far in gels.Entities:
Keywords: crack bifurcation; fracture resistance; isochoric conditions; network topology; thermoresponsive hydrogels; volume-phase transition
Year: 2016 PMID: 27159115 DOI: 10.1002/adma.201600514
Source DB: PubMed Journal: Adv Mater ISSN: 0935-9648 Impact factor: 30.849