Literature DB >> 27151931

Stabilization of molecular lanthanide polysulfides by bulky scorpionate ligands.

Marcel Kühling1, Robert McDonald, Phil Liebing, Liane Hilfert, Michael J Ferguson, Josef Takats, Frank T Edelmann.   

Abstract

Well-defined lanthanide polysulfide complexes containing S4(2-) and S5(2-) ligands, the samarium(iii) pentasulfide complex Sm(Tp(iPr2))(κ(1)-3,5-(i)Pr2Hpz)(S5) and the tetrasulfide-bridged binuclear ytterbium(iii) complex (μ-S4)[Yb(Tp(iPr2))(κ(1)-3,5-(i)Pr2Hpz)(κ(2)-3,5-(i)Pr2pz)]2 (Tp(iPr2) = hydro-tris(3,5-diisopropylpyrazolyl)borate), have been synthesized and structurally characterized by single-crystal X-ray diffraction.

Entities:  

Year:  2016        PMID： 27151931     DOI： 10.1039/c6dt01439a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Formation and structural characterization of a europium(II) mono(scorpionate) complex and a sterically crowded pyraza-bole.

Authors:  Phil Liebing; Marcel Kühling; Josef Takats; Liane Hilfert; Frank T Edelmann
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-11-21

2.  Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides.

Authors:  Conrad A P Goodwin; Benjamin L L Réant; Gianni F Vettese; Jon G C Kragskow; Marcus J Giansiracusa; Ida M DiMucci; Kyle M Lancaster; David P Mills; Stephen Sproules
Journal:  Inorg Chem       Date:  2020-05-18       Impact factor: 5.165

3.  Photoluminescence of Homoleptic Lanthanide Complexes With Tris(benzotriazol-1-yl)borate.

Authors:  Marco Bortoluzzi; Valentina Ferraro; Federica Sartor
Journal:  J Fluoresc       Date:  2021-07-13       Impact factor: 2.217
  3 in total

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