| Literature DB >> 27151859 |
Tao Liu1, Gunwoo Kim2, Javier Carretero-González1, Elizabeth Castillo-Martínez1, Clare P Grey3.
Abstract
We described a lithium-oxygen (Li-O2) battery comprising a graphene electrode, a dimethoxyethane-based electrolyte, and H2O and lithium iodide (LiI) additives, lithium hydroxide (LiOH) being the predominant discharge product. We demonstrate, in contrast to the work of Shen et al., that the chemical reactivity between LiOH and the triiodide ion (I3 (-)) to form IO3 (-) indicates that LiOH can be removed on charging; the electrodes do not clog, even after multiple cycles, confirming that solid products are reversibly removed.Entities:
Year: 2016 PMID: 27151859 DOI: 10.1126/science.aaf1652
Source DB: PubMed Journal: Science ISSN: 0036-8075 Impact factor: 47.728