Literature DB >> 27145065

Mild C-H/C-C Activation by Z-Selective Cobalt Catalysis.

Daniel Zell1, Qingqing Bu1, Milica Feldt1, Lutz Ackermann2.   

Abstract

Cationic cobalt complexes enable unprecedented cobalt-catalyzed C-H/C-C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C-H/C-C cleavage at room temperature, and delivered Z-alkenes with excellent diastereocontrol.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−C cleavage; C−H activation; cobalt; homogeneous catalysis; stereoselectivity

Year:  2016        PMID： 27145065     DOI： 10.1002/anie.201601778

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  12 in total

1.  Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

Authors:  Xiaowei Wu; Haitao Ji
Journal:  J Org Chem       Date:  2018-09-21       Impact factor: 4.354

2.  Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate.

Authors:  Liyuan Ding; Chunbing Yu; Zhenqiang Zhao; Feifei Li; Jian Zhang; Guofu Zhong
Journal:  J Vis Exp       Date:  2017-06-21       Impact factor: 1.355

3.  Cobalt-Catalyzed Intramolecular Alkyne/Benzocyclobutenone Coupling: C-C Bond Cleavage via a Tetrahedral Dicobalt Intermediate.

Authors:  Zixi Zhu; Xinghan Li; Sicong Chen; Peng-Hao Chen; Brent A Billett; Zhongxing Huang; Guangbin Dong
Journal:  ACS Catal       Date:  2017-12-22       Impact factor: 13.084

Review 4.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

5.  Manganese-catalyzed allylation via sequential C-H and C-C/C-Het bond activation.

Authors:  Qingquan Lu; Felix J R Klauck; Frank Glorius
Journal:  Chem Sci       Date:  2017-02-24       Impact factor: 9.825

Review 6.  Recent Advances on Synthetic Methodology Merging C-H Functionalization and C-C Cleavage.

Authors:  Hamid Azizollahi; José-Antonio García-López
Journal:  Molecules       Date:  2020-12-13       Impact factor: 4.411

7.  Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.

Authors:  Soham Maity; Pravas Dolui; Rajesh Kancherla; Debabrata Maiti
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825

8.  Additive-Free Pd-Catalyzed α-Allylation of Imine-Containing Heterocycles.

Authors:  Marko Kljajic; Johannes G Puschnig; Hansjörg Weber; Rolf Breinbauer
Journal:  Org Lett       Date:  2016-12-12       Impact factor: 6.005

Review 9.  Hydroarylations by cobalt-catalyzed C-H activation.

Authors:  Rajagopal Santhoshkumar; Chien-Hong Cheng
Journal:  Beilstein J Org Chem       Date:  2018-08-29       Impact factor: 2.883

10.  Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage.

Authors:  Chenhui Chen; Hongliang Wang; Yufeng Sun; Jiayan Cui; Jianbo Xie; Yang Shi; Shijia Yu; Xin Hong; Zhan Lu
Journal:  iScience       Date:  2020-03-17
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