Tough Polymer Aerogels Incorporating a Conformal Inorganic Coating for Low Flammability and Durable Hydrophobicity.

Both inorganic and polymeric aerogels are well-known in the materials field. Inorganic aerogels are generally susceptible to brittle fracture, while polymeric aerogels tend to exhibit low modului and high flammability. To overcome these disadvantages, we introduce a new approach to the design of aerogels. A microporous poly(vinyl alcohol) (PVA) aerogel/silica nanocomposite was prepared by growing a silica conformal coating onto a PVA aerogel scaffold. Such aerogel/silica nanocomposites show significant improvement in their mechanical properties over either individual component. The nanocomposites show excellent fire resistance since the silica conformal coating serves as a barrier for heat transfer and mass loss of the coated organic materials. After a fluorocarbon silane treatment, the nanocomposites also show durable superhydrophobicity.