| Literature DB >> 27139714 |
Nathaniel J Hartmann1, Guang Wu, Trevor W Hayton.
Abstract
The "masked" terminal nickel sulfide complexes [K(L)][(L(tBu))Ni(II)(S)] (L(tBu) = {(2,6-(i)Pr2C6H3)NC((t)Bu)}2CH, L = 18-crown-6, 2,2,2-cryptand) activate CS2 to give the trithiocarbonate products [(L(tBu))Ni(II)(S,S:κ2-CS3)](-) or [(S,S:κ2-CS3)Ni(II){S,S:κ2-CS2(L(tBu))}](-), further confirming the nucleophilicity of the sulfide (S(2-)) ligand in these complexes.Entities:
Year: 2016 PMID： 27139714 DOI： 10.1039/c6dt00885b
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390