Literature DB >> 27135905

Synthesis of Cyclooctatetraenes through a Palladium-Catalyzed Cascade Reaction.

Sarah Blouin1, Vincent Gandon2,3, Gaëlle Blond4, Jean Suffert5.   

Abstract

Reported is a cascade reaction leading to fully substituted cyclooctatetraenes. This unexpected transformation likely proceeds through a unique 8π electrocyclization reaction of a ene triyne. DFT computations provide the mechanistic basis of this surprizing reaction.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkenes; density functional calculations; electrocyclizations; palladium; reaction mechanisms

Year:  2016        PMID： 27135905     DOI： 10.1002/anie.201602586

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Stabilizing a different cyclooctatetraene stereoisomer.

Authors:  Longfei Li; Ming Lei; Yaoming Xie; Henry F Schaefer; Bo Chen; Roald Hoffmann
Journal:  Proc Natl Acad Sci U S A       Date:  2017-08-28       Impact factor: 11.205

2.  Palladium-catalyzed regio- and stereoselective synthesis of aryl and 3-indolyl-substituted 4-methylene-3,4-dihydroisoquinolin-1(2H)-ones.

Authors:  Valeria Nori; Antonio Arcadi; Armando Carlone; Fabio Marinelli; Marco Chiarini
Journal:  Beilstein J Org Chem       Date:  2020-05-20       Impact factor: 2.883

3.  Synthesis of Aromatic Rings Embedded in Polycyclic Scaffolds by Triyne Cycloaddition: Competition between Carbonylative and Non-Carbonylative Pathways.

Authors:  Laura Salacz; Nicolas Girard; Jean Suffert; Gaëlle Blond
Journal:  Molecules       Date:  2019-02-07       Impact factor: 4.411

4.  Sequential Insertion of Alkynes, Alkenes, and CO into the Pd-C Bond of ortho-Palladated Primary Phenethylamines: from η3-Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines.

Authors:  José-Antonio García-López; María-José Oliva-Madrid; Delia Bautista; José Vicente; Isabel Saura-Llamas
Journal:  Organometallics       Date:  2021-01-29       Impact factor: 3.876
  4 in total

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