| Literature DB >> 27128526 |
Yueyue Zhu1, Tieqiao Chen1, Shan Li1, Shigeru Shimada2, Li-Biao Han2.
Abstract
A Pd-catalyzed dehydrogenative phosphorylation of thiols is developed. A variety of thiols dehydrogenatively couple readily with all three kinds of P(O)-H compounds, i.e., H-phosphonates, H-phosphinates, and secondary phosphine oxides, providing a general access to the valuable phosphorothioates including the P-chiral compounds. A plausible mechanism is proposed.Entities:
Year: 2016 PMID： 27128526 DOI： 10.1021/jacs.6b03112
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419