| Literature DB >> 27124237 |
Zhuliang Zhong1, Gaoyuan Zhao1, Dengyu Xu1, Baobiao Dong1, Dengpeng Song1, Xingang Xie1, Xuegong She2,3.
Abstract
The first bioinspired total syntheses of (-) kravanhins A and C were accomplished from a labdane diterpenoid derivative. The key reactions involve a photooxidation and a one-pot sequential aldol cyclization and lactonization, which provide a new plausible biosynthetic pathway for the kravanhins and other symbiotic members.Entities:
Keywords: biosynthesis; natural products; one-pot reactions; terpenoids; total synthesis
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Year: 2016 PMID： 27124237 DOI： 10.1002/asia.201600398
Source DB: PubMed Journal: Chem Asian J ISSN： 1861-471X