Literature DB >> 27122120

Insertion of (t)BuNC into thorium-phosphorus and thorium-arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry.

Andrew C Behrle1, Justin R Walensky1.   

Abstract

The reactivity of thorium-phosphido and thorium-arsenido bonds was probed using tert-butyl isocyanide, (t)BuNC. Reaction of (C5Me5)2Th[E(H)R]2, E = P, As; R = 2,4,6-(i)Pr3C6H2, 2,4,6-Me3C6H2 with (t)BuNC affords the first phosphaazaallene and arsaazaallene moieties with an f-element.

Entities:  

Year:  2016        PMID： 27122120     DOI： 10.1039/c6dt00776g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-03-09       Impact factor: 14.919

2.  Crystal structures of metallocene complexes with uranium-germanium bonds.

Authors:  Michael L Tarlton; Steven P Kelley; Justin R Walensky
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2021-11-09

3.  Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands.

Authors:  Robert J Ward; Pokpong Rungthanaphatsophon; Iker Del Rosal; Steven P Kelley; Laurent Maron; Justin R Walensky
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825

4.  Thorium-phosphorus triamidoamine complexes containing Th-P single- and multiple-bond interactions.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2016-09-29       Impact factor: 14.919
  4 in total

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