Literature DB >> 27118921

On well-posedness of variational models of charged drops.

Cyrill B Muratov1, Matteo Novaga2.   

Abstract

Electrified liquids are well known to be prone to a variety of interfacial instabilities that result in the onset of apparent interfacial singularities and liquid fragmentation. In the case of electrically conducting liquids, one of the basic models describing the equilibrium interfacial configurations and the onset of instability assumes the liquid to be equipotential and interprets those configurations as local minimizers of the energy consisting of the sum of the surface energy and the electrostatic energy. Here we show that, surprisingly, this classical geometric variational model is mathematically ill-posed irrespective of the degree to which the liquid is electrified. Specifically, we demonstrate that an isolated spherical droplet is never a local minimizer, no matter how small is the total charge on the droplet, as the energy can always be lowered by a smooth, arbitrarily small distortion of the droplet's surface. This is in sharp contrast to the experimental observations that a critical amount of charge is needed in order to destabilize a spherical droplet. We discuss several possible regularization mechanisms for the considered free boundary problem and argue that well-posedness can be restored by the inclusion of the entropic effects resulting in finite screening of free charges.

Keywords:  Coulomb fission; free boundary; geometric variational problem; ill-posedness; screening

Year:  2016        PMID: 27118921      PMCID: PMC4841488          DOI: 10.1098/rspa.2015.0808

Source DB:  PubMed          Journal:  Proc Math Phys Eng Sci        ISSN: 1364-5021            Impact factor:   2.704


  7 in total

1.  Shape oscillations and stability of charged microdroplets.

Authors:  D Duft; H Lebius; B A Huber; C Guet; T Leisner
Journal:  Phys Rev Lett       Date:  2002-08-06       Impact factor: 9.161

2.  Coulomb fission: Rayleigh jets from levitated microdroplets.

Authors:  Denis Duft; Tobias Achtzehn; Rene Müller; Bernd A Huber; Thomas Leisner
Journal:  Nature       Date:  2003-01-09       Impact factor: 49.962

3.  Applying a potential across a biomembrane: electrostatic contribution to the bending rigidity and membrane instability.

Authors:  Tobias Ambjörnsson; Michael A Lomholt; Per Lyngs Hansen
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2007-05-25

4.  Ion formation from charged droplets: Roles of geometry, energy, and time.

Authors:  J B Fenn
Journal:  J Am Soc Mass Spectrom       Date:  1993-07       Impact factor: 3.109

5.  Discrete Charge Distributions in Dielectric Droplets.

Authors: 
Journal:  J Colloid Interface Sci       Date:  1998-10-01       Impact factor: 8.128

6.  Simulations of coulombic fission of charged inviscid drops.

Authors:  J C Burton; P Taborek
Journal:  Phys Rev Lett       Date:  2011-04-05       Impact factor: 9.161

7.  Numerical simulations of electrostatically driven jets from nonviscous droplets.

Authors:  M Garzon; L J Gray; J A Sethian
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2014-03-13
  7 in total

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