| Literature DB >> 27116426 |
Dashan Li1,2, Ting Wu1,2, Kangjiang Liang1,2, Chengfeng Xia1,3.
Abstract
A Curtius-like rearrangement of hydroxamates to isocyanates was discovered. This reaction was initiated from an iron(II)-nitrenoid complex, which was generated by the iron(II)-catalyzed cleavage of N-O bonds of functionalized hydroxamates. To demonstrate the efficiency of this new Curtius-like rearrangement in synthetic chemistry, a biomimetic strategy for the one-pot preparation of bisindolylmethanes was developed.Entities:
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Year: 2016 PMID： 27116426 DOI： 10.1021/acs.orglett.6b00864
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005