| Literature DB >> 27108786 |
Tapas Kumar Achar1, Saikat Maiti1, Prasenjit Mal1.
Abstract
Iodinium cation (I(+) or IOAc) was produced from the combination of phenyliodine diacetate (PIDA) and iodine. I(+) facilitated the direct vicinal difunctionalization of olefins to α-azido, α-trideuteriomethoxy, α-2,2,2-trifluoroethoxy and α-acyloxy alkyl iodides via cation-π interaction at room temperature and under transition-metal free conditions.Entities:
Year: 2016 PMID： 27108786 DOI： 10.1039/c6ob00532b
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876