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Literature DB >> 27087168

Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets.

Jonas Warneke¹, Carsten Jenne, Johannes Bernarding, Vladimir A Azov, Markus Plaumann.

Abstract

A gas phase binding study revealed strong intrinsic intermolecular interactions between dianionic halogenated closo-dodecaborates [B12X12](2-) and several neutral organic receptors. Oxidation of a tetrathiafulvalene host allowed switching between two host-guest binding modes in a supramolecular complex. Complexes of β-cyclodextrin with [B12F12](2-) show remarkable stability in the gas phase and were successfully tested as carriers for the delivery of boron clusters into cancer cells.

Entities: Chemical Disease

Mesh：

Substances：

Year: 2016 PMID： 27087168 DOI： 10.1039/c6cc01233g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. Gas-Phase Fragmentation of Host-Guest Complexes of Cyclodextrins and Polyoxometalates.

Authors: Pei Su; Andrew J Smith; Jonas Warneke; Julia Laskin
Journal: J Am Soc Mass Spectrom Date: 2019-08-14 Impact factor: 3.109

2. Ex Vivo and In Vivo Evaluation of Dodecaborate-Based Clusters Encapsulated in Ferumoxytol Nanoparticles.

Authors: Nicholas A Bernier; James Teh; Derek Reichel; Joanne L Zahorsky-Reeves; J Manuel Perez; Alexander M Spokoyny
Journal: Langmuir Date: 2021-11-29 Impact factor: 3.882

3. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B₁₂H₁₁NH₃]^.

Authors: Yuanbin Zhang; Yuji Sun; Tao Wang; Jiyong Liu; Bernhard Spingler; Simon Duttwyler
Journal: Molecules Date: 2018-11-29 Impact factor: 4.411

4. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class.

Authors: Vera V Voinova; Nikita A Selivanov; Ivan V Plyushchenko; Mikhail F Vokuev; Alexander Yu Bykov; Ilya N Klyukin; Alexander S Novikov; Andrey P Zhdanov; Mikhail S Grigoriev; Igor A Rodin; Konstantin Yu Zhizhin; Nikolay T Kuznetsov
Journal: Molecules Date: 2021-01-05 Impact factor: 4.411

Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets.

1. Gas-Phase Fragmentation of Host-Guest Complexes of Cyclodextrins and Polyoxometalates.

2. Ex Vivo and In Vivo Evaluation of Dodecaborate-Based Clusters Encapsulated in Ferumoxytol Nanoparticles.

3. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B₁₂H₁₁NH₃]^.

4. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class.

5. Self-organizing layers from complex molecular anions.

Review 6. The Chaotropic Effect as an Assembly Motif in Chemistry.

7. Synthesis, Electronic Properties and Reactivity of [B₁₂ X₁₁ (NO₂ )]^2- (X=F-I) Dianions.

Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets.

1. Gas-Phase Fragmentation of Host-Guest Complexes of Cyclodextrins and Polyoxometalates.

2. Ex Vivo and In Vivo Evaluation of Dodecaborate-Based Clusters Encapsulated in Ferumoxytol Nanoparticles.

3. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH₃].

4. Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion-Novel Members of Diboroheterocycle Class.

5. Self-organizing layers from complex molecular anions.

Review 6. The Chaotropic Effect as an Assembly Motif in Chemistry.

7. Synthesis, Electronic Properties and Reactivity of [B12 X11 (NO2 )]2- (X=F-I) Dianions.

3. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B₁₂H₁₁NH₃]^.

7. Synthesis, Electronic Properties and Reactivity of [B₁₂ X₁₁ (NO₂ )]^2- (X=F-I) Dianions.