Literature DB >> 27086679

A strongly greenish-blue-emitting Cu4Cl4 cluster with an efficient spin-orbit coupling (SOC): fast phosphorescence versus thermally activated delayed fluorescence.

Xu-Lin Chen1, Rongmin Yu, Xiao-Yuan Wu, Dong Liang, Ji-Hui Jia, Can-Zhong Lu.   

Abstract

In this communication, we report a new greenish-blue-emitting Cu(i) complex, Cu4Cl4(NP)2, a with high photoluminescence quantum yield of 90% and a short decay time of 9.9 μs. Due to the strong SOC combined with the small activation energy ΔEST, the emission at room temperature consists of approximately equivalent fast phosphorescence and TADF.

Entities:  

Year:  2016        PMID： 27086679     DOI： 10.1039/c6cc00809g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Thermally Activated Delayed Fluorescence in CuI Complexes Originating from Restricted Molecular Vibrations.

Authors:  Guangfu Li; Roberto S Nobuyasu; Baohua Zhang; Yun Geng; Bing Yao; Zhiyuan Xie; Dongxia Zhu; Guogang Shan; Weilong Che; Likai Yan; Zhongmin Su; Fernando B Dias; Martin R Bryce
Journal:  Chemistry       Date:  2017-08-10       Impact factor: 5.236

2.  Cu(I) Complexes of Multidentate N,C,N- and P,C,P-Carbodiphosphorane Ligands and Their Photoluminescence.

Authors:  Marius Klein; Nemrud Demirel; Alexander Schinabeck; Hartmut Yersin; Jörg Sundermeyer
Journal:  Molecules       Date:  2020-09-01       Impact factor: 4.411

Review 3.  TADF: Enabling luminescent copper(i) coordination compounds for light-emitting electrochemical cells.

Authors:  Catherine E Housecroft; Edwin C Constable
Journal:  J Mater Chem C Mater       Date:  2021-10-12       Impact factor: 7.393

4.  A Red-Emitting Cu(I)-Halide Cluster Phosphor with Near-Unity Photoluminescence Efficiency for High-Power wLED Applications.

Authors:  Wenjiang Zhaxi; Miao Li; Jing Wu; Luying Liu; Zetao Huang; Huixian Miao; Xiao Ma; Shenlong Jiang; Qun Zhang; Wei Huang; Dayu Wu
Journal:  Molecules       Date:  2022-07-11       Impact factor: 4.927

5.  Observation of Contrary Thermo-responsive Trend for Single Crystal and Powder Samples in Mechano-, Thermo- and Solvato-responsive Luminescent Cubane [Ag4I4L4] Cluster.

Authors:  Shi-Li Li; Min Han; Bin Wu; Jie Wang; Fu-Qiang Zhang; Xian-Ming Zhang
Journal:  Sci Rep       Date:  2017-10-12       Impact factor: 4.379

6.  Investigation of Luminescent Triplet States in Tetranuclear CuI Complexes: Thermochromism and Structural Characterization.

Authors:  Pit Boden; Patrick Di Martino-Fumo; Jasmin M Busch; Florian R Rehak; Sophie Steiger; Oliver Fuhr; Martin Nieger; Daniel Volz; Willem Klopper; Stefan Bräse; Markus Gerhards
Journal:  Chemistry       Date:  2021-01-15       Impact factor: 5.236

7.  Fabrication of a Solution-Processed White Light Emitting Diode Containing a Single Dimeric Copper(I) Emitter Featuring Combined TADF and Phosphorescence.

Authors:  Gang Cheng; Dongling Zhou; Uwe Monkowius; Hartmut Yersin
Journal:  Micromachines (Basel)       Date:  2021-11-30       Impact factor: 2.891
  7 in total

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