Electron monochromator-mass spectrometer instrument for negative ion analysis of electronegative compounds.

Electron monochromators designed for the production of low-energy electrons (0-15 eV) with nearly monoenergetic distributions have been available for many decades. The concept of adapting the electron monochromator as an ion source onto mass spectrometers for the purpose of electron capture negative ion-mass spectrometric (ECNI-MS) analyses is only now being realized. Two different analyzers, a quadrupole and a double focusing sector instrument, have recently been retrofitted with electron monochromators to test their utility as analytical instruments for the detection of environmental compounds and chemical agents. Electron energy scans of compounds in these classes reveal unique negative ion resonances, which can be used as an additional analytical dimension of information for compound identification and confirmation. Electron currents of 430 μA at 0.03 eV electron energy are now available from the electron monochromator, which will provide sufficient electron flux to meet modern standards for trace level analyses. The narrowest electron energy spread achieved has been ±0.07 eV (fwhm). The electron monochromator-mass spectrometer (EM-MS) instrument has been interfaced to a gas chromatograph (GC), and this system (GC/EM-MS) was used to record ion chromatograms of mixtures of polychlorinated compounds. Regioselective ion loss, resulting from dissociative electron capture by the parent molecule, is electron-energy dependent and can be monitored with the EM-MS instrument. Finally, positive ion spectra produced with monoenergetic electrons have also been recorded. © 1997 John Wiley & Sons, Inc.