| Literature DB >> 27077402 |
James A Bellow1, Sebastian A Stoian2, Johan van Tol2, Andrew Ozarowski2, Richard L Lord3, Stanislav Groysman1.
Abstract
The formally Co(IV) carbene Co(OR)2(═CPh2) is formed upon the reaction of diphenyldiazomethane with the cobalt bis(alkoxide) precursor Co(OR)2(THF)2. Structural, spectroscopic, and theoretical studies demonstrate that Co(OR)2(═CPh2) has significant high-valent Co(IV)═CPh2 character with non-negligible spin density on the carbene moiety.Entities:
Year: 2016 PMID： 27077402 DOI： 10.1021/jacs.6b02747
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419