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Literature DB >> 27075435

Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides.

Abstract

This review is a comprehensive survey of the last 10 years of research on ammonia-borane and amine-borane dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The review also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent on the CMH of choice) and the catalysts efficiency (in terms of equivalents of H2 produced and relative reaction rates) are provided throughout the discussion.

Entities: Chemical

Year: 2016 PMID： 27075435 DOI： 10.1021/acs.chemrev.6b00043

Source DB: PubMed Journal: Chem Rev ISSN： 0009-2665 Impact factor: 60.622

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Cited

22 in total

1. Characterization of B-H agostic compounds involved in the dehydrogenation of amine-boranes by group 4 metallocenes.

Authors: Jingwen Zhu; Emilie-Laure Zins; Mohammad Esmaïl Alikhani
Journal: J Mol Model Date: 2016-11-25 Impact factor: 1.810

2. Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission.

Authors: Qi Tang; Shi-Jun Li; Xiaohan Ye; Teng Yuan; Kai Zhao; Ying He; Chuan Shan; Lukasz Wojtas; David Richardson; Yu Lan; Xiaodong Shi
Journal: Chem Sci Date: 2022-04-18 Impact factor: 9.969

3. Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

Authors: Liam J Donnelly; Simon Parsons; Carole A Morrison; Stephen P Thomas; Jason B Love
Journal: Chem Sci Date: 2020-09-09 Impact factor: 9.825

Review 4. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors: Amit Kumar; Prosenjit Daw; David Milstein
Journal: Chem Rev Date: 2021-11-02 Impact factor: 60.622

Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides.

1. Characterization of B-H agostic compounds involved in the dehydrogenation of amine-boranes by group 4 metallocenes.

2. Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission.

3. Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

Review 4. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

5. A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes.

6. S_E2 reaction in noncarbon system: Metal-halide catalysis for dehydrogenation of ammonia borane.

Review 7. Iron Catalyzed Dehydrocoupling of Amine- and Phosphine-Boranes.

8. Magnesocenophane-Catalyzed Amine Borane Dehydrocoupling.

Review 9. Defunctionalisation catalysed by boron Lewis acids.

Review 10. Metathesis by Partner Interchange in σ-Bond Ligands: Expanding Applications of the σ-CAM Mechanism.

Ammonia-Borane and Amine-Borane Dehydrogenation Mediated by Complex Metal Hydrides.

1. Characterization of B-H agostic compounds involved in the dehydrogenation of amine-boranes by group 4 metallocenes.

2. Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission.

3. Synthesis and structures of anionic rhenium polyhydride complexes of boron-hydride ligands and their application in catalysis.

Review 4. Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

5. A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes.

6. SE2 reaction in noncarbon system: Metal-halide catalysis for dehydrogenation of ammonia borane.

Review 7. Iron Catalyzed Dehydrocoupling of Amine- and Phosphine-Boranes.

8. Magnesocenophane-Catalyzed Amine Borane Dehydrocoupling.

Review 9. Defunctionalisation catalysed by boron Lewis acids.

Review 10. Metathesis by Partner Interchange in σ-Bond Ligands: Expanding Applications of the σ-CAM Mechanism.

6. S_E2 reaction in noncarbon system: Metal-halide catalysis for dehydrogenation of ammonia borane.