Literature DB >> 27067645

Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): deprotonation-induced switching among nonaromatic, Möbius aromatic, and Hückel antiaromatic species.

Won-Young Cha1, Takanori Soya, Takayuki Tanaka, Hirotaka Mori, Yongseok Hong, Sangsu Lee, Kyu Hyung Park, Atsuhiro Osuka, Dongho Kim.   

Abstract

Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Möbius aromatic species and dianinonic square Hückel antiaromatic species, depending upon the amount of TBAF.

Entities:  

Year:  2016        PMID： 27067645     DOI： 10.1039/c6cc02051h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Stereochemical plasticity modulates cooperative binding in a CoII12L6 cuboctahedron.

Authors:  Felix J Rizzuto; Jonathan R Nitschke
Journal:  Nat Chem       Date:  2017-04-10       Impact factor: 24.427

2.  Reversible π-system switching of thiophene-fused thiahexaphyrins by solvent and oxidation/reduction.

Authors:  Tomohiro Higashino; Atsushi Kumagai; Shigeyoshi Sakaki; Hiroshi Imahori
Journal:  Chem Sci       Date:  2018-08-14       Impact factor: 9.825

3.  Circular linkage of intramolecular multi-hydrogen bonding frameworks through nucleophilic substitutions of β-dicarbonyls onto cyanuric chloride and subsequent tautomerisation.

Authors:  Ayano Awatani; Masaaki Suzuki
Journal:  RSC Adv       Date:  2020-10-23       Impact factor: 4.036
  3 in total

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