| Literature DB >> 27043308 |
Sayantan Das1, Debobrata Paul1, Rajib Kumar Goswami1.
Abstract
A convergent strategy for the stereoselective total synthesis of biologically active marine natural product biselyngbyolide B has been developed. Key strategies of this synthesis include Jamison protocol of trans-hydroalumination/allylation for installation of C18-C23 olefin moiety and intramolecular Heck coupling for macrocyclization.Entities:
Mesh:
Substances:
Year: 2016 PMID: 27043308 DOI: 10.1021/acs.orglett.6b00713
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005