Literature DB >> 27028161

Selective Metal-Free Hydrosilylation of CO2 Catalyzed by Triphenylborane in Highly Polar, Aprotic Solvents.

Debabrata Mukherjee1, Daniel F Sauer1, Alessandro Zanardi1, Jun Okuda2.   

Abstract

Triphenylborane (BPh3 ) in highly polar, aprotic solvents catalyzes hydrosilylation of CO2 effectively under mild conditions to provide silyl formates with high chemoselectivity (>95 %) and without over-reduction. This system also promotes reductive hydrosilylation of tertiary amides as well as dehydrogenative coupling of silane with alcohols.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  boranes; carbon dioxide; chemoselectivity; hydrosilylation; solvent effects

Year:  2016        PMID： 27028161     DOI： 10.1002/chem.201601006

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  6 in total

1.  Investigation of main group promoted carbon dioxide reduction.

Authors:  Brena L Thompson; Zachariah M Heiden
Journal:  Tetrahedron       Date:  2019-02-15       Impact factor: 2.457

2.  Selective Catalytic Frustrated Lewis Pair Hydrogenation of CO2 in the Presence of Silylhalides.

Authors:  Tongtong Wang; Maotong Xu; Andrew R Jupp; Zheng-Wang Qu; Stefan Grimme; Douglas W Stephan
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-03       Impact factor: 16.823

3.  N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si-H σ-Bond Activation and Catalytic (De)hydrosilylation.

Authors:  Valerio Fasano; James E Radcliffe; Liam D Curless; Michael J Ingleson
Journal:  Chemistry       Date:  2016-11-22       Impact factor: 5.236

4.  Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations.

Authors:  Valerio Fasano; Michael J Ingleson
Journal:  Chemistry       Date:  2017-01-18       Impact factor: 5.236

5.  Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation.

Authors:  Kori A Andrea; Francesca M Kerton
Journal:  RSC Adv       Date:  2019-08-23       Impact factor: 3.361

Review 6.  From CO2 activation to catalytic reduction: a metal-free approach.

Authors:  Sreejyothi P; Swadhin K Mandal
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825
  6 in total

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