Literature DB >> 27022648

Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand.

Andrea Di Giuseppe1, Roberto De Luca2, Ricardo Castarlenas2, Jesús J Pérez-Torrente1, Marcello Crucianelli3, Luis A Oro4.   

Abstract

The regioselective double hydrophosphination of alkynes mediated by rhodium catalysts is presented. The distinctive stereoelectronic properties of the NHC ligand prevent the catalyst deactivation by diphosphine coordination thereby allowing for the closing of a productive catalytic cycle.

Entities:  

Year:  2016        PMID： 27022648     DOI： 10.1039/c5cc09156j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Catalyst-free hydrophosphination of alkenes in presence of 2-methyltetrahydrofuran: a green and easy access to a wide range of tertiary phosphines.

Authors:  Damien Bissessar; Julien Egly; Thierry Achard; Pascal Steffanut; Stéphane Bellemin-Laponnaz
Journal:  RSC Adv       Date:  2019-08-30       Impact factor: 3.361

2.  Rhodium-NHC-Catalyzed gem-Specific O-Selective Hydropyridonation of Terminal Alkynes.

Authors:  María Galiana-Cameo; Raúl Romeo; Asier Urriolabeitia; Vincenzo Passarelli; Jesús J Pérez-Torrente; Victor Polo; Ricardo Castarlenas
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-19       Impact factor: 16.823

Review 3.  Broken Promises? On the Continued Challenges Faced in Catalytic Hydrophosphination.

Authors:  Samantha Lau; Thomas M Hood; Ruth L Webster
Journal:  ACS Catal       Date:  2022-08-22       Impact factor: 13.700
  3 in total

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