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Literature DB >> 27006205

Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer.

Michael Neustetter¹, Andreas Mauracher, Paulo Limão-Vieira, Stephan Denifl.

Abstract

We observed the bare W2(+) metal cation upon electron ionization of the weakly bound W(CO)6 dimer. This metal cation can be only observed due to the fast conversion of the weak cluster bond into a strong covalent bond between the metal moieties.

Entities: Chemical Disease

Year: 2016 PMID： 27006205 DOI： 10.1039/c6cp00558f

Source DB: PubMed Journal: Phys Chem Chem Phys ISSN： 1463-9076 Impact factor: 3.676

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Cited

2 in total

1. Interactions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)₆).

Authors: Jusuf M Khreis; João Ameixa; Filipe Ferreira da Silva; Stephan Denifl
Journal: Beilstein J Nanotechnol Date: 2017-12-04 Impact factor: 3.649

2. Comprehensive investigation of the electronic excitation of W(CO)₆ by photoabsorption and theoretical analysis in the energy region from 3.9 to 10.8 eV.

Authors: Mónica Mendes; Khrystyna Regeta; Filipe Ferreira da Silva; Nykola C Jones; Søren Vrønning Hoffmann; Gustavo García; Chantal Daniel; Paulo Limão-Vieira
Journal: Beilstein J Nanotechnol Date: 2017-10-23 Impact factor: 3.649

2 in total

Complete ligand loss in electron ionization of the weakly bound organometallic tungsten hexacarbonyl dimer.

1. Interactions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)6).

2. Comprehensive investigation of the electronic excitation of W(CO)6 by photoabsorption and theoretical analysis in the energy region from 3.9 to 10.8 eV.

1. Interactions of low-energy electrons with the FEBID precursor chromium hexacarbonyl (Cr(CO)₆).

2. Comprehensive investigation of the electronic excitation of W(CO)₆ by photoabsorption and theoretical analysis in the energy region from 3.9 to 10.8 eV.