Literature DB >> 27001895

Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols.

Jai Anand Garg1, Subrata Chakraborty, Yehoshoa Ben-David, David Milstein.   

Abstract

The first example of hydrogenation of amides homogeneously catalyzed by an earth-abundant metal complex is reported. The reaction is catalyzed by iron PNP pincer complexes. A wide range of secondary and tertiary N-substituted 2,2,2-trifluoroacetamides were hydrogenated to form amines and trifluoroethanol.

Entities:  

Year:  2016        PMID： 27001895     DOI： 10.1039/c6cc01505k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

1.  Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

Authors:  Kristian E Dalle; Julien Warnan; Jane J Leung; Bertrand Reuillard; Isabell S Karmel; Erwin Reisner
Journal:  Chem Rev       Date:  2019-02-15       Impact factor: 60.622

2.  The Ferraquinone-Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity.

Authors:  Alexander Dauth; Urs Gellrich; Yael Diskin-Posner; Yehoshoa Ben-David; David Milstein
Journal:  J Am Chem Soc       Date:  2017-02-13       Impact factor: 15.419

3.  A new route to N-aromatic heterocycles from the hydrogenation of diesters in the presence of anilines.

Authors:  Yiping Shi; Paul C J Kamer; David J Cole-Hamilton; Michelle Harvie; Emma F Baxter; Kate J C Lim; Peter Pogorzelec
Journal:  Chem Sci       Date:  2017-08-08       Impact factor: 9.825

4.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

5.  Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight.

Authors:  Sayan Kar; Michael Rauch; Amit Kumar; Gregory Leitus; Yehoshoa Ben-David; David Milstein
Journal:  ACS Catal       Date:  2020-04-21       Impact factor: 13.084

6.  Hydrogenative Depolymerization of Nylons.

Authors:  Amit Kumar; Niklas von Wolff; Michael Rauch; You-Quan Zou; Guy Shmul; Yehoshoa Ben-David; Gregory Leitus; Liat Avram; David Milstein
Journal:  J Am Chem Soc       Date:  2020-08-11       Impact factor: 15.419

7.  Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts.

Authors:  Bo Han; Miaomiao Zhang; Hongmei Jiao; Haojie Ma; Jijiang Wang; Yuqi Zhang
Journal:  RSC Adv       Date:  2021-12-15       Impact factor: 4.036

8.  Multifaceted catalytic hydrogenation of amides via diverse activation of a sterically confined bipyridine-ruthenium framework.

Authors:  Takashi Miura; Masayuki Naruto; Katsuaki Toda; Taiki Shimomura; Susumu Saito
Journal:  Sci Rep       Date:  2017-05-16       Impact factor: 4.379

9.  Rational selection of co-catalysts for the deaminative hydrogenation of amides.

Authors:  Lluís Artús Suàrez; Upul Jayarathne; David Balcells; Wesley H Bernskoetter; Nilay Hazari; Martín Jaraiz; Ainara Nova
Journal:  Chem Sci       Date:  2020-01-20       Impact factor: 9.825

10.  Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism.

Authors:  Thomas Leischner; Lluis Artús Suarez; Anke Spannenberg; Kathrin Junge; Ainara Nova; Matthias Beller
Journal:  Chem Sci       Date:  2019-10-08       Impact factor: 9.825
  10 in total

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