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Literature DB >> 26996920

Ruthenium(II)-Catalyzed Decarboxylative C-H Activation: Versatile Routes to meta-Alkenylated Arenes.

N Y Phani Kumar¹, Alexander Bechtoldt¹, Keshav Raghuvanshi¹, Lutz Ackermann².

Abstract

Ruthenium(II) bis(carboxylate)s proved highly effective for two decarboxylative C-H alkenylation strategies. The decarboxylation proceeded efficiently at rather low temperatures. The unique versatility of the decarboxylative ruthenium(II) catalysis is reflected in the oxidative olefinations with alkenes as well as the redox-neutral hydroarylations of alkynes.

Entities: Chemical

Keywords: C−H activation; alkenes; arenes; reaction mechanisms; ruthenium

Year: 2016 PMID： 26996920 DOI： 10.1002/anie.201600490

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

11 in total

1. C-H activation: Good things come in threes.

Authors: Marco Simonetti; Igor Larrosa
Journal: Nat Chem Date: 2016-11-22 Impact factor: 24.427

2. Electrochemical Decarboxylative N-Alkylation of Heterocycles.

Authors: Tao Sheng; Hai-Jun Zhang; Ming Shang; Chi He; Julien C Vantourout; Phil S Baran
Journal: Org Lett Date: 2020-09-17 Impact factor: 6.005

3. Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis.

Authors: Faben A Cruz; Yamin Zhu; Quentin D Tercenio; Zengming Shen; Vy M Dong
Journal: J Am Chem Soc Date: 2017-07-25 Impact factor: 15.419

4. Convergent Synthesis of (R)-Silodosin via Decarboxylative Cross-Coupling.

Authors: Tie-Gen Chen; Lucas Mele; Olivier Jentzer; Dominique Delbrayelle; Pierre-Georges Echeverria; Julien C Vantourout; Phil S Baran
Journal: Tetrahedron Lett Date: 2021-07-24 Impact factor: 2.032

5. Ligand-Promoted Meta-C-H Arylation of Anilines, Phenols, and Heterocycles.

Authors: Peng Wang; Marcus E Farmer; Xing Huo; Pankaj Jain; Peng-Xiang Shen; Mette Ishoey; James E Bradner; Steven R Wisniewski; Martin D Eastgate; Jin-Quan Yu
Journal: J Am Chem Soc Date: 2016-07-19 Impact factor: 15.419

Review 6. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors: Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal: Chem Soc Rev Date: 2018-08-28 Impact factor: 54.564

Ruthenium(II)-Catalyzed Decarboxylative C-H Activation: Versatile Routes to meta-Alkenylated Arenes.

1. C-H activation: Good things come in threes.

2. Electrochemical Decarboxylative N-Alkylation of Heterocycles.

3. Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis.

4. Convergent Synthesis of (R)-Silodosin via Decarboxylative Cross-Coupling.

5. Ligand-Promoted Meta-C-H Arylation of Anilines, Phenols, and Heterocycles.

Review 6. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

7. Ruthenium-Catalyzed C-H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides.

Review 8. Last Decade of Unconventional Methodologies for the Synthesis of Substituted Benzofurans.

9. meta-C-H arylation of fluoroarenes via traceless directing group relay strategy.

10. Carboxylate-directed C-H allylation with allyl alcohols or ethers.