Literature DB >> 26996764

Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane.

Zeguo Fang1, Nawaf Al-Maharik, Alexandra M Z Slawin, Michael Bühl, David O'Hagan.   

Abstract

The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

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Year:  2016        PMID: 26996764     DOI: 10.1039/c6cc01348a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Organofluorine chemistry: Difluoromethylene motifs spaced 1,3 to each other imparts facial polarity to a cyclohexane ring.

Authors:  Mathew J Jones; Ricardo Callejo; Alexandra M Z Slawin; Michael Bühl; David O'Hagan
Journal:  Beilstein J Org Chem       Date:  2016-12-22       Impact factor: 2.883

2.  Understanding the Conformational Behavior of Fluorinated Piperidines: The Origin of the Axial-F Preference.

Authors:  Zackaria Nairoukh; Felix Strieth-Kalthoff; Klaus Bergander; Frank Glorius
Journal:  Chemistry       Date:  2020-05-12       Impact factor: 5.236

  2 in total

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