Literature DB >> 26996326

Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis.

Lei Zhu1, Lian-Sheng Wang, Bojie Li, Boqiao Fu, Cheng-Pan Zhang, Wei Li.   

Abstract

We report herein a single component Ir photoredox catalyst which is capable of catalyzing the hydrotrifluoromethylation of terminal alkenes and Michael acceptors with sodium triflinate (Langlois reagent) in methanol under irradiation at room temperature. Various synthetically useful functional groups, including ester, amide, ether, aldehyde, sulfone, ketone and aryl boronate, are well tolerated in this reaction.

Entities:  

Year:  2016        PMID： 26996326     DOI： 10.1039/c6cc01944g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

2.  Copper(i) reagent-promoted hydroxytrifluoromethylation of enamides: flexible synthesis of substituted-3-hydroxy-2-aryl-3-(2,2,2-trifluoro-1-arylethyl)isoindolin-1-one.

Authors:  Qing Wang; Peng Shi; Runsheng Zeng
Journal:  RSC Adv       Date:  2018-07-19       Impact factor: 4.036

3.  CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na.

Authors:  Hélène Guyon; Hélène Chachignon; Dominique Cahard
Journal:  Beilstein J Org Chem       Date:  2017-12-19       Impact factor: 2.883

Review 4.  Quantum Dots Compete at the Acme of MXene Family for the Optimal Catalysis.

Authors:  Yuhua Liu; Wei Zhang; Weitao Zheng
Journal:  Nanomicro Lett       Date:  2022-08-02

5.  Visible light-mediated difluoroalkylation of electron-deficient alkenes.

Authors:  Vyacheslav I Supranovich; Vitalij V Levin; Marina I Struchkova; Jinbo Hu; Alexander D Dilman
Journal:  Beilstein J Org Chem       Date:  2018-07-02       Impact factor: 2.883

6.  Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me4N][XCF3] (X = S, Se) and TfOH.

Authors:  Jin Shi; Cheng-Pan Zhang
Journal:  Molecules       Date:  2020-10-03       Impact factor: 4.411
  6 in total

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