A Solar Cell That Is Triggered by Sun and Rain.

All-weather solar cells are promising in solving the energy crisis. A flexible solar cell is presented that is triggered by combining an electron-enriched graphene electrode with a dye-sensitized solar cell. The new solar cell can be excited by incident light on sunny days and raindrops on rainy days, yielding an optimal solar-to-electric conversion efficiency of 6.53 % under AM 1.5 irradiation and current over microamps as well as a voltage of hundreds of microvolts by simulated raindrops. The formation of π-electron|cation electrical double-layer pseudocapacitors at graphene/raindrop interface is contributable to current and voltage outputs at switchable charging-discharging process. The new concept can guide the design of advanced all-weather solar cells.