Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Dithioacetal Exchange: A New Reversible Reaction for Dynamic Combinatorial Chemistry.

Literature DB >> 26990904

Dithioacetal Exchange: A New Reversible Reaction for Dynamic Combinatorial Chemistry.

A Gastón Orrillo¹, Andrea M Escalante¹, Ricardo L E Furlan^2,3.

Abstract

Reversibility of dithioacetal bond formation is reported under acidic mild conditions. Its utility for dynamic combinatorial chemistry was explored by combining it with orthogonal disulfide exchange. In such a setup, thiols are positioned at the intersection of both chemistries, constituting a connecting node between temporally separated networks.

Entities: Chemical

Keywords: dithioacetal exchange; dynamic combinatorial chemistry; reversible reaction; systems chemistry

Year: 2016 PMID： 26990904 DOI： 10.1002/chem.201600208

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

Keyword Cloud
Cited

7 in total

1. Expanding the Thiol-X Toolbox: Photoinitiation and Materials Application of the Acid-Catalyzed Thiol-ene (ACT) Reaction.

Authors: Bryan P Sutherland; Mukund Kabra; Christopher J Kloxin
Journal: Polym Chem Date: 2021-01-13 Impact factor: 5.582

Dithioacetal Exchange: A New Reversible Reaction for Dynamic Combinatorial Chemistry.

1. Expanding the Thiol-X Toolbox: Photoinitiation and Materials Application of the Acid-Catalyzed Thiol-ene (ACT) Reaction.

2. Antiparallel Dynamic Covalent Chemistries.

3. Engineering multilayer chemical networks.

4. Direct Synthesis of Unsymmetrical Dithioacetals.

5. Teaching an Old Compound New Tricks: Reversible Transamidation in Maleamic Acids.

6. Dynamic Covalent Chemistry of Aldehyde Enamines: Bi^III - and Sc^III -Catalysis of Amine-Enamine Exchange.

7. A tetrahedral molecular cage with a responsive vertex.