Literature DB >> 26989848

Carboxylation of Phenols with CO2 at Atmospheric Pressure.

Junfei Luo1,2, Sara Preciado2, Pan Xie1, Igor Larrosa3.   

Abstract

A convenient and efficient method for the ortho-carboxylation of phenols under atmospheric CO2 pressure has been developed. This method provides an alternative to the previously reported Kolbe-Schmitt method, which requires very high pressures of CO2 . The addition of a trisubstituted phenol has proved essential for the successful carboxylation of phenols with CO2 at standard atmospheric pressure, allowing the efficient preparation of a broad variety of salicylic acids.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Kolbe-Schmitt reaction; carbon dioxide; phenols; salicylic acids; synthetic methods

Mesh：

Substances：

Year:  2016        PMID： 26989848     DOI： 10.1002/chem.201601114

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  7 in total

1.  Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2.

Authors:  Si-Shun Yan; Lei Zhu; Jian-Heng Ye; Zhen Zhang; He Huang; Huiying Zeng; Chao-Jun Li; Yu Lan; Da-Gang Yu
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825

2.  Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings.

Authors:  Gregory J P Perry; Jacob M Quibell; Adyasha Panigrahi; Igor Larrosa
Journal:  J Am Chem Soc       Date:  2017-08-08       Impact factor: 15.419

3.  Photocarboxylation of Benzylic C-H Bonds.

Authors:  Qing-Yuan Meng; Tobias E Schirmer; Anna Lucia Berger; Karsten Donabauer; Burkhard König
Journal:  J Am Chem Soc       Date:  2019-07-11       Impact factor: 15.419

4.  Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis.

Authors:  Basudev Sahoo; Peter Bellotti; Francisco Juliá-Hernández; Qing-Yuan Meng; Stefano Crespi; Burkhard König; Ruben Martin
Journal:  Chemistry       Date:  2019-06-06       Impact factor: 5.236

5.  First Phenol Carboxylation with CO2 on Carbon Nanostructured C@Fe-Al2O3 Hybrids in Aqueous Media under Mild Conditions.

Authors:  Feliciano Calvo-Castañera; Jesús Álvarez-Rodríguez; Nuria Candela; Ángel Maroto-Valiente
Journal:  Nanomaterials (Basel)       Date:  2021-01-13       Impact factor: 5.076

6.  Volatile Constituent Analysis of Wintergreen Essential Oil and Comparison with Synthetic Methyl Salicylate for Authentication.

Authors:  Pawan Kumar Ojha; Darbin Kumar Poudel; Sabita Dangol; Anil Rokaya; Sujan Timsina; Prabodh Satyal; William N Setzer
Journal:  Plants (Basel)       Date:  2022-04-17

Review 7.  C-H Carboxylation of Aromatic Compounds through CO2 Fixation.

Authors:  Junfei Luo; Igor Larrosa
Journal:  ChemSusChem       Date:  2017-08-16       Impact factor: 8.928
  7 in total

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