| Literature DB >> 26978243 |
Gustavo M Borrajo-Calleja1, Vincent Bizet1, Clément Mazet1.
Abstract
A novel enantioselective Pd-catalyzed intermolecular carboetherification of dihydrofurans is reported. The in situ generation of chiral bis-phosphine mono-oxide ligands is crucial, and a general catalytic system has been identified based on this approach. It provides access to a variety of fused tetrahydrofurobenzofurans in consistently high yield and enantiomeric excess.Entities:
Year: 2016 PMID: 26978243 DOI: 10.1021/jacs.6b02158
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419